9-Minute Semivolatiles Analysis with Appendix IX on Rxi-5ms by U.S. EPA Method 8270D

Peaks
1.1,4-Dioxane-d8 (IS)
2.1,4-Dioxane
3.N-Nitrosodimethylamine
4.Pyridine
5.Ethyl methacrylate
6.2-Picoline
7.N-Nitrosomethylethylamine
8.Methyl methanesulfonate
9.2-Fluorophenol (SS)
10.N-Nitrosodiethylamine
11.Ethyl methanesulfonate
12.Benzaldehyde
13.Phenol-d6 (SS)
14.Phenol
15.Aniline
16.Pentachloroethane
17.Bis(2-chloroethyl) ether
18.2-Chlorophenol
19.1,3-Dichlorobenzene
20.1,4-Dichlorobenzene-d4 (IS)
21.1,4-Dichlorobenzene
22.Benzyl alcohol
23.1,2-Dichlorobenzene
24.2-Methylphenol
25.Bis(2-Chloroisopropyl)ether
26.p-Cresol (4-methylphenol)
27.m-Cresol (3-methylphenol)
28.Acetophenone
29.N-Nitrosopyrrolidine
30.N-Nitrosomorpholine
31.N-Nitrosodi-n-propylamine
32.o-Toluidine
33.Hexachloroethane
34.Nitrobenzene-d5 (SS)
35.Nitrobenzene
36.N-Nitrosopiperidine
37.Isophorone
38.2-Nitrophenol
39.2,4-Dimethylphenol
40.Bis(2-chloroethoxy)methane
41.Benzoic acid
42.2,4-Dichlorophenol
43.α,α-Dimethylphenethylamine (Phentermine)
44.1,2,4-Trichlorobenzene
45.Naphthalene-d8 (IS)
46.Naphthalene
47.4-Chloroaniline
48.2,6-Dichlorophenol
49.Hexachloropropene
50.Hexachlorobutadiene
51.Caprolactam
52.N-Nitroso-n-butylamine
53.1,4-Phenylenediamine
54.4-Chloro-3-methylphenol
55.Isosafrole I (isomer)
56.2-Methylnaphthalene
57.1-Methylnaphthalene
58.Isosafrole II (isomer)
59.1,2,4,5-Tetrachlorobenzene
60.Hexachlorocyclopentadiene
61.2,4,6-Trichlorophenol
62.2,4,5-Trichlorophenol
63.2-Fluorobiphenyl (SS)
64.Safrole
65.Biphenyl
66.2-Chloronaphthalene
67.1-Chloronaphthalene
68.Diphenyl ether
69.2-Nitroaniline
70.1,4-Naphthoquinone
71.1,4-Dinitrobenzene
72.Dimethyl phthalate
Peaks
73.1,3-Dinitrobenzene
74.2,6-Dinitrotoluene
75.Acenaphthylene
76.1,2-Dinitrobenzene
77.3-Nitroaniline
78.Acenaphthene-d10 (IS)
79.Acenaphthene
80.2,4-Dinitrophenol
81.4-Nitrophenol
82.Dibenzofuran
83.Pentachlorobenzene
84.2,4-Dinitrotoluene
85.1-Naphthalamine
86.2,3,5,6-Tetrachlorophenol
87.2-Naphthalamine
88.2,3,4,6-Tetrachlorophenol
89.Diethyl phthalate
90.4-Chlorophenyl phenyl ether
91.Fluorene
92.2-Methyl-5-nitroaniline
93.4-Nitroaniline
94.4,6-Dinitro-2-methylphenol
95.N-Nitrosodiphenylamine
96.1,2-Diphenylhydrazine (as Azobenzene)
97.2,4,6-Tribromophenol (SS)
98.1,3,5-Trinitrobenzene
99.Diallate
100.Phenacetin
101.4-Bromophenyl phenyl ether
102.Hexachlorobenzene
103.Atrazine
104.4-Aminobiphenyl
105.Pentachlorophenol
106.Propyzamide
107.Pentachloronitrobenzene
108.Phenanthrene-d10 (IS)
109.Phenanthrene
110.Anthracene
111.Carbazole
112.di-n-Butyl phthalate
113.4-Nitroquinoline oxide
114.Isodrin
115.Fluoranthene
116.Benzidine
117.Pyrene-d10 (SS)
118.Pyrene
119.Aramite I (isomer)
120.p-Terphenyl-d14 (SS)
121.Aramite II (isomer)
122.Dimethylaminoazobenzene
123.Chlorobenzilate
124.3,3'-Dimethylbenzidine
125.Kepone
126.n-Butyl benzyl phthalate
127.Bis(2-ethylhexyl) adipate
128.2-Acetylaminofluorine
129.3,3'-Dichlorobenzidine
130.Chrysene-d12 (IS)
131.Benz[a]anthracene
132.Chrysene
133.Bis(2-ethylhexyl) phthalate
134.Di-n-octyl phthalate
135.Benzo[b]fluoranthene
136.Benzo[k]fluoranthene
137.7,12-Dimethylbenzo[a]anthracene
138.Benzo[a]pyrene
139.Perylene-d12 (IS)
140.3-Methylcholanthrene
141.Dibenz[a,j]acridine
142.Indeno[1,2,3-cd]pyrene
143.Dibenz[a,h]anthracene
144.Benzo[ghi]perylene
image
GC_EV1328
ColumnRxi®-5ms, 10 m, 0.18 mm ID, 0.18 µm
using Rxi®-5ms 2 m, 0.18 mm ID,
with 0.4 mm OD matched press-fit, BGB (cat.# 2525LD)
SampleRevised SV internal standard mix (cat.# 31886)
Revised B/N surrogate mix (cat.# 31888)
Acid surrogate mix (4/89 SOW) (cat.# 31063)
8270 MegaMix® (cat.# 31850)
8270 Benzidines mix (cat.# 31852)
Benzoic acid (cat.# 31879)
Appendix IX mix #1, revised (cat.# 32459)
Appendix IX mix #2 (cat.# 31806)
Diluent:Dichloromethane
Conc.:20 µg/mL (1.0 ng on column)
Injection
Inj. Vol.:0.5 µL split (split ratio 10:1)
Liner:2 mm Split Precision® liner w/deact. wool (cat.# 20824)
Inj. Temp.:275 °C
Split Vent Flow Rate:9 mL/min
Oven
Oven Temp.:35 °C (hold 0.5 min) to 115 °C at 95 °C/min to 240 °C at 65 °C/min to 265 °C at 6 °C/min to 330 °C at 35 °C/min (hold 1 min)
Carrier GasHe, constant flow
Flow Rate:0.9 mL/min
DetectorMS
Mode:Scan
Scan Program:
GroupStart Time
(min)
Scan Range
(amu)
Scan Rate
(scans/sec)
10.7535-45011.47
23.6735-4506.48
Transfer Line Temp.:320 °C
Analyzer Type:Quadrupole
Source Type:Inert
Drawout Plate:3mm ID
Source Temp.:330 °C
Quad Temp.:180 °C
Electron Energy:70 eV
Solvent Delay Time:0.75 min
Tune Type:BFB
Ionization Mode:EI
InstrumentAgilent 7890A GC & 5975C MSD
NotesThe 10 m analytical and 2 m guard columns used in this application are segments of a 20 m x 0.18 mm ID x 0.18 µm df Rxi®-5ms column (cat.# 13402). The 20 m column was cut to yield one 10 m analytical column and five 2 m guard columns.
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8270

,

appendix IX

,

semivolatiles

,

benzo[b]fluoranthene

,

2,4-dinitrophenol

,

DNP

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